Anodization Treatment of Ti6Al4V in Electrolytes Containing HF
Keywords:
anodization, nanotube, nanopore, oxide, HF concentration
Abstract
The Ti6Al4V alloy is already well-known likely material for implant applications. As well as pure titanium, Ti6Al4V alloy possess the ability to form spontaneously a thin passive oxide layer on the surface. This oxide layer provides an enhanced biocompatibility and may be optimum for the osseointegration if it is applied a tailoring of the surface topology and chemistry. The present paper addresses a study of Ti6Al4V surface modification by anodization as function of HF concentration in electrolyte and time, with the purpose to achieve an ordered porous titanium oxide layer. Prior to the anodization treatment the as-prepared surfaces were microstructurally characterized by SEM, EDX and XRD. The oxidized surfaces were subjected to SEM measurement in order to observe the achieved morphology.
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References
[1]. D. M. Brunette, P. Tengvall, M. Textor, P. Thomsen - Titanium in Medicine: Material Science, Surface Science, Engineering, Biological Responses and Medical Applications, 1st edition Springer; Berlin, (2001), pp.14-19.
[2]. M.M. Lohrengel - Thin anodic oxide layers on aluminium and other valve metals: high field regime, Materials Science and Engineering, Vol. R11, pp.243-294, (1993).
[3]. X. Liu, P. Chu, C. Ding - Surface modification of titanium, titanium alloys, and related materials for biomedical applications, Materials Science and Engineering: Reports: Vol. R47, pp.49-121, (2004).
[4]. K. Subramani - Titanium Surface Modification Techniques for Implant Fabrication – From Microscale to the Nanoscale, Journal of Biomimetics, Biomaterials, and Tissue Engineering. Vol. 5, pp.39-56, (2010).
[5]. V. Zwilling, E. Darquel Ceretti - Structure and physicochemistry of anodic oxide films on titanium and TA6V alloy, Surface and Interface Analysis, Vol.27, pp. 629-637, (1999).
[6]. J.M. Macak, H. Tsuchiya, L. Taveira, A. Ghicov, P. Schmuki - Self-organized nanotubular oxide layers on Ti-6Al-7Nb and Ti-6Al4V formed by anodization in NH4F solutions, Journal of Biomedical Materials Research. Part A, Vol. 75, pp. 928-33, (2005).
[7]. E. Matykina, a. Conde, J. de Damborenea, D.M.Y. Marero, M. a. Arenas - Growth of TiO2-based nanotubes on Ti–6Al–4V alloy, Electrochimica Acta, Vol.56, pp.9209-9218, 2011.
[8]. H. Lukáčová, B. Plešingerová, M. Vojtko, G. Bán - Electrochemical treatment of Ti6Al4V (1. Part) - Acta Metallurgica Slovaca, Vol.16, pp. 186-193, (2010).
[9]. H.-C. Choe - Nanotubular surface and morphology of Ti-binary and Ti-ternary alloys for biocompatibility, Thin Solid Films, Vol.519, pp.4652-4657, (2011).
[10]. E. Matykina, J.M. Hernandez-López, A. Conde, C. Domingo, J.J. de Damborenea, M. A. Arenas - Morphologies of nanostructured TiO2 doped with F on Ti–6Al–4V alloy, Electrochimica Acta, Vol.56, pp.2221-2229, (2011).
[11]. A. Kaczmarek, T. Klekiel, E. Krasicka-Cydzik - Fluoride concentration effect on the anodic growth of self-aligned oxide nanotube array on Ti6Al7Nb alloy, Surface and Interface Analysis, Vol.42, pp.510-514, (2010).
[12]. G. Crawford, N. Chawla - Porous hierarchical TiO2 nanostructures: Processing and microstructure relationships, Acta Materialia, Vol.57, pp. 854-867, (2009).
[13]. S.E. Pust, D. Scharnweber, C. Nunes Kirchner, G. Wittstock - Heterogeneous Distribution of Reactivity on Metallic Biomaterials: Scanning Probe Microscopy Studies of the Biphasic Ti Alloy Ti6Al4V, Advanced Materials, Vol.19, pp.878-882, (2007).
[14]. P. Roy, S. Berger, P. Schmuki - TiO2 nanotubes: synthesis and applications, Angewandte Chemie (International Ed. in English), Vol. 50, pp.2904-39, (2011).
[2]. M.M. Lohrengel - Thin anodic oxide layers on aluminium and other valve metals: high field regime, Materials Science and Engineering, Vol. R11, pp.243-294, (1993).
[3]. X. Liu, P. Chu, C. Ding - Surface modification of titanium, titanium alloys, and related materials for biomedical applications, Materials Science and Engineering: Reports: Vol. R47, pp.49-121, (2004).
[4]. K. Subramani - Titanium Surface Modification Techniques for Implant Fabrication – From Microscale to the Nanoscale, Journal of Biomimetics, Biomaterials, and Tissue Engineering. Vol. 5, pp.39-56, (2010).
[5]. V. Zwilling, E. Darquel Ceretti - Structure and physicochemistry of anodic oxide films on titanium and TA6V alloy, Surface and Interface Analysis, Vol.27, pp. 629-637, (1999).
[6]. J.M. Macak, H. Tsuchiya, L. Taveira, A. Ghicov, P. Schmuki - Self-organized nanotubular oxide layers on Ti-6Al-7Nb and Ti-6Al4V formed by anodization in NH4F solutions, Journal of Biomedical Materials Research. Part A, Vol. 75, pp. 928-33, (2005).
[7]. E. Matykina, a. Conde, J. de Damborenea, D.M.Y. Marero, M. a. Arenas - Growth of TiO2-based nanotubes on Ti–6Al–4V alloy, Electrochimica Acta, Vol.56, pp.9209-9218, 2011.
[8]. H. Lukáčová, B. Plešingerová, M. Vojtko, G. Bán - Electrochemical treatment of Ti6Al4V (1. Part) - Acta Metallurgica Slovaca, Vol.16, pp. 186-193, (2010).
[9]. H.-C. Choe - Nanotubular surface and morphology of Ti-binary and Ti-ternary alloys for biocompatibility, Thin Solid Films, Vol.519, pp.4652-4657, (2011).
[10]. E. Matykina, J.M. Hernandez-López, A. Conde, C. Domingo, J.J. de Damborenea, M. A. Arenas - Morphologies of nanostructured TiO2 doped with F on Ti–6Al–4V alloy, Electrochimica Acta, Vol.56, pp.2221-2229, (2011).
[11]. A. Kaczmarek, T. Klekiel, E. Krasicka-Cydzik - Fluoride concentration effect on the anodic growth of self-aligned oxide nanotube array on Ti6Al7Nb alloy, Surface and Interface Analysis, Vol.42, pp.510-514, (2010).
[12]. G. Crawford, N. Chawla - Porous hierarchical TiO2 nanostructures: Processing and microstructure relationships, Acta Materialia, Vol.57, pp. 854-867, (2009).
[13]. S.E. Pust, D. Scharnweber, C. Nunes Kirchner, G. Wittstock - Heterogeneous Distribution of Reactivity on Metallic Biomaterials: Scanning Probe Microscopy Studies of the Biphasic Ti Alloy Ti6Al4V, Advanced Materials, Vol.19, pp.878-882, (2007).
[14]. P. Roy, S. Berger, P. Schmuki - TiO2 nanotubes: synthesis and applications, Angewandte Chemie (International Ed. in English), Vol. 50, pp.2904-39, (2011).
Published
2013-03-15
How to Cite
1.
STOICA E-D, FEDOROV FS, NICOLAE M, UHLEMANN M, GEBERT A. Anodization Treatment of Ti6Al4V in Electrolytes Containing HF. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Mar.2013 [cited 16Nov.2024];36(1):10-3. Available from: https://gup.ugal.ro/ugaljournals/index.php/mms/article/view/2845
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