Investigation of Titanium Hydride Produced from Titanium Waste
Résumé
The work presents an original method for titanium hydride production by hydrogenation and dehydrogenation of titanium waste in a specially designed for this purpose vacuum chamber. Laboratory quantities of titanium hydride were prepared using LaNi5 hydrogen accumulator as a source of pure hydrogen. Chemical, X-ray, DTA, TG and granulometric analysis of the obtained hydride were made. The analyses carried out in the temperature range, 680-1070 К, DTA, TG and mass-spectrometry analysis allowed determining the activation energy of decomposition of the obtained TiH2 which was approximately E = -135.5 kJ/mol and the standard enthalpy of formation ΔH = -140 kJ/mol.
Références
[1]. ***, www.roskill.com.
[2]. Georgiev, J., Y. Lukarski. Laboratory Installation for Producing TiH2 by Hydrogen. Processing. 5th Congress of the Society of Metallurgists of Macedonia with International Participation, Sept. 17-20, 2008, Ohrid, Macedonia, CD ISBN 978-9989-9571-4-7, M8-02-E.
[3]. Kissinger, H. E., Reaction kinetics in differential thermal analysis, Anal. Chem. 29 (1957) 1702-1706.
[4]. Jing-wei Zhao, Hua Ding, Xue-feng Tian, Wen-juan Zhao and Hong-liang Hou Chin. J. Chem. Phys. 21 (2008) 569-574.
[5]. E. Koenigsberger, G.Eriksson and W. A. Oates, Journal of alloys and Compounds, 299 (2000) 148-152.
[6]. A. San-Martin and F. D. Manchester, Bulletin of Alloy Phase Diagrams, 8(1) (1987) 30-42.
[2]. Georgiev, J., Y. Lukarski. Laboratory Installation for Producing TiH2 by Hydrogen. Processing. 5th Congress of the Society of Metallurgists of Macedonia with International Participation, Sept. 17-20, 2008, Ohrid, Macedonia, CD ISBN 978-9989-9571-4-7, M8-02-E.
[3]. Kissinger, H. E., Reaction kinetics in differential thermal analysis, Anal. Chem. 29 (1957) 1702-1706.
[4]. Jing-wei Zhao, Hua Ding, Xue-feng Tian, Wen-juan Zhao and Hong-liang Hou Chin. J. Chem. Phys. 21 (2008) 569-574.
[5]. E. Koenigsberger, G.Eriksson and W. A. Oates, Journal of alloys and Compounds, 299 (2000) 148-152.
[6]. A. San-Martin and F. D. Manchester, Bulletin of Alloy Phase Diagrams, 8(1) (1987) 30-42.
Publiée
2010-12-15
Comment citer
1.
LUKARSKI Y, GEORGIEV J, ANESTIEV L, GAVRILOVA R, BEJAN S. Investigation of Titanium Hydride Produced from Titanium Waste. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15déc.2010 [cité 3juill.2024];33(4):84-8. Available from: https://gup.ugal.ro/ugaljournals/index.php/mms/article/view/2982
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