Equilibrium Study Regarding Crystal Violet Dye Adsorption on Raspberry Leaves Powder
Keywords:
dye adsorption, crystal violet, raspberry leaves, equilibrium isotherms
Abstract
This work focuses on the crystal violet removal from aqueous solution using raspberry leaves powder as adsorbent materials. SEM and colour analyses were used to characterize the adsorbent surface. The influence of pH, adsorbent dose and initial dye concentration was studied. Equilibrium modeling was performed to characterize the adsorption process and to determine the maximum adsorption capacity. Sips isotherm characterizes the adsorption and the maximum adsorption capacity, 264.5 (mg/g) was better compared with other similar adsorbents. The obtained results indicate that adsorbent material, obtained from raspberry leaves, is very suitable to be used for crystal violet removal from aqueous solutions.
Downloads
Download data is not yet available.
References
[1]. Pang X., Sellaoui L., Franco D., Dotto G. L., Georgin J., Bajahzar A., Belmabrouk H., Ben Lamine A., Bonilla-Petriciolet A., Lia Z., Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria bark and palm cactus: Experimental study and theoretical modeling via monolayer and double layer statistical physics models, Chemical Engineering Journal, 378, 122101, 2019.
[2]. Shakoor S., Nasar, A., Adsorptive decontamination of synthetic wastewater containing crystal violet dye by employing Terminalia arjuna sawdust waste, Groundwater for Sustainable Development, 7, p. 30-38, 2018.
[3]. Shoukat S., Bhatti H. N., Iqbal M., Noreen, S., Mango stone biocomposite preparation and application for crystal violet adsorption: A mechanistic study, Microporous and Mesoporous Materials, 239, p. 180-189, 2017.
[4]. Zamouche M., Habib A., Saaidia K., Lehocine M. B., Batch mode for adsorption of crystal violet by cedar cone forest waste, SN Applied Sciences, 2, 198, 2020.
[5]. Chahinez H.O., Abdelkader O., Leila Y., Tran H. N., Onestage preparation of palm petiole-derived biochar: Characterization and application for adsorption of crystal violet dye in water, Environmental Technology & Innovation, 19, 100872, 2020.
[6]. Franco D. S. P., Fagundes J. L. S., Georgin J., Salaua N. P. G., Dotto G. L., A mass transfer study considering intraparticle diffusion and axial dispersion for fixed-bed adsorption of crystal violet on pecan pericarp (Carya illinoensis), Chemical Engineering Journal, 397, 125423, 2020.
[7]. Kosar Hashemi Y., Tavakkoli Yaraki M., Ghanbari S., Heidarpoor Saremi L., Givianrad M. H., Photodegradation of organic water pollutants under visible light using anatase F, N codoped TiO2/SiO2 nanocomposite: Semi-pilot plant experiment and density functional theory calculations, Chemosphere, 275, 129903, 2021.
[8]. Loulidi I., Boukhlifi F., Ouchabi M., Amar A., Jabri M., Kali A., Chraibi S., Hadey C., Aziz F., Adsorption of crystal violet onto an agricultural waste residue: kinetics, isotherm, thermodynamics and mechanism of adsorption, The Scientific World Journal, 2020, 5873521, 2020.
[9]. Georgin J., Franco D. S. P., Netto M. S., Allasia D., Oliveira M. L. S., Dotto G. L., Evaluation of Ocotea puberula bark powder (OPBP) as an effective adsorbent to uptake crystal violet from colored effluents: Alternative kinetic approaches, Environmental Science and Pollution Research, 27, p. 25727-25739, 2020.
[10]. Chevallier A., Encyclopedia of Herbal Medicine: 550 Herbs and Remedies for Common Ailments, 3rd ed., DK Publishing: New York, NY, USA, p. 264, 2016.
[11]. Chwil M., Kostryco M., Histochemical assays of secretory trichomes and the structure and content of mineral nutrients in Rubus idaeus L. leaves, Protoplasma, 257, p. 119-139, 2020.
[12]. Yang Y., Yin X., Zhang D., Lu J., Wang X., Isolation, Structural Characterization and Macrophage Activation Activity of an Acidic Polysaccharide from Raspberry Pulp, Molecules, 27, 1674, 2022.
[13]. Mosoarca G., Popa S., Vancea C., Dan M., Boran S., Removal of Methylene Blue from Aqueous Solutions Using a New Natural Lignocellulosic Adsorbent - Raspberry (Rubus idaeus) Leaves Powder, Polymers, 14, 1966, 2022.
[14]. Piccin J. S., Cadaval T. R. S., de Pinto L. A. A., Dotto G. L., Adsorption isotherms in liquid phase: Experimental, modeling and interpretations, In: Adsorption Processes for Water Treatment and Purification, Bonilla-Petriciolet A., Mendoza-Castillo D., Reynel-Avila H. (Eds.), Springer, Switzerland, p. 19-51, 2017.
[15]. Fabryanty R., Valencia C., Soetaredjo F. E., Putro J. N., Santoso S.P., Kurniawan A., Ju Y. H., Ismadji S., Removal of crystal violet dye by adsorption using bentonite - alginate composite, Journal of Environmental Chemical Engineering, 5(6), p. 5677-5687, 2017.
[16]. Filho A. C. D., Mazzocato A. C., Dotto G. L., Thue P. S., Pavan F. A., Eragrostis plana Nees as a novel eco-friendly adsorbent for removal of crystal violet from aqueous solutions, Environmental Science and Pollution Research, 24, p. 19909-19919, 2017.
[17]. Keereerak A., Chinpa W., A potential biosorbent from Moringa oleifera pod husk for crystal violet adsorption: Kinetics, isotherms, thermodynamic and desorption studies, Science Asia, 46, p. 186-194, 2020.
[18]. Jain S., Jayaram R. V., Removal of basic dyes from aqueous solution by low-cost adsorbent: Wood apple shell (Feronia acidissima), Desalination, 250(3), p. 921-927, 2010.
[19]. Silveira M. B., Pavan F. A., Gelos N. F., Lima E. C., Dias S. L., Punica granatum shell preparation, characterization, and use for crystal violet removal from aqueous solution, Clean-Soil Air Water, 42(7), p. 939-946, 2014.
[20]. Ahmad R., Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP), Journal of Hazardous Materials, 171, p. 767-773, 2009.
[21]. Wang X. S., Liu X., Wen L., Zhou Y., Jiang Y., Li Z., Comparison of Basic Dye Crystal Violet Removal from Aqueous Solution by Low-Cost Biosorbents, Separation Science and Technology, 43, p. 3712-3731, 2008.
[22]. Muhammad U. L., Zango Z. U., Kadir H. A., Usman A., Crystal violet removal from aqueous solution using corn stalk biosorbent, Science World Journal, 14, p. 133-138, 2019.
[23]. Mosoarca G., Vancea C., Popa S., Boran S., Optimization of crystal violet adsorption on common lilac tree leaf powder as natural adsorbent material, Global NEST Journal, 24(1), p. 87-96, 2022.
[24]. Saha P. D., Chakraborty S., Chowdhury S., Batch and continuous (fixed-bed column) bisorption of crystal violet by Artocarpus heterophyllus (jackfruit) leaf powder, Colloids and Surfaces B: Biointerfaces, 92, p. 262-270, 2012.
[25]. Chakraborty S., Chowdhury S., Saha P. D., Insight into biosorption equilibrium, kinetics and thermo-dynamics of crystal violet onto Ananas comosus (pineapple) leaf powder, Applied Water Science, 2, p. 135-141, 2012.
[26]. Kulkarni M. R., Revanth T., Anirudh A., Bhat P., Removal of crystal violet dye from aqueous solution using water hyacinth: equilibrium, kinetics and thermodynamics study, Resource-Efficient Technologies, 3(1), p. 71-77, 2017.
[28]. Saeed A., Sharif M., Iqbal M., Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption, Journal of Hazardous Materials, 179(1-3), p. 564-572, 2010.
[29]. Nieva A. D., Avena L. G. S., Pascual M. A. M., Pamintuan K. R. S., Characterization of Powdered Pineapple (Ananas comosus) Crown Leaves as Adsorbent for Crystal Violet in Aqueous Solutions, IOP Conf. Series: Earth and Environmental Science, 563, 012010, 2020.
[2]. Shakoor S., Nasar, A., Adsorptive decontamination of synthetic wastewater containing crystal violet dye by employing Terminalia arjuna sawdust waste, Groundwater for Sustainable Development, 7, p. 30-38, 2018.
[3]. Shoukat S., Bhatti H. N., Iqbal M., Noreen, S., Mango stone biocomposite preparation and application for crystal violet adsorption: A mechanistic study, Microporous and Mesoporous Materials, 239, p. 180-189, 2017.
[4]. Zamouche M., Habib A., Saaidia K., Lehocine M. B., Batch mode for adsorption of crystal violet by cedar cone forest waste, SN Applied Sciences, 2, 198, 2020.
[5]. Chahinez H.O., Abdelkader O., Leila Y., Tran H. N., Onestage preparation of palm petiole-derived biochar: Characterization and application for adsorption of crystal violet dye in water, Environmental Technology & Innovation, 19, 100872, 2020.
[6]. Franco D. S. P., Fagundes J. L. S., Georgin J., Salaua N. P. G., Dotto G. L., A mass transfer study considering intraparticle diffusion and axial dispersion for fixed-bed adsorption of crystal violet on pecan pericarp (Carya illinoensis), Chemical Engineering Journal, 397, 125423, 2020.
[7]. Kosar Hashemi Y., Tavakkoli Yaraki M., Ghanbari S., Heidarpoor Saremi L., Givianrad M. H., Photodegradation of organic water pollutants under visible light using anatase F, N codoped TiO2/SiO2 nanocomposite: Semi-pilot plant experiment and density functional theory calculations, Chemosphere, 275, 129903, 2021.
[8]. Loulidi I., Boukhlifi F., Ouchabi M., Amar A., Jabri M., Kali A., Chraibi S., Hadey C., Aziz F., Adsorption of crystal violet onto an agricultural waste residue: kinetics, isotherm, thermodynamics and mechanism of adsorption, The Scientific World Journal, 2020, 5873521, 2020.
[9]. Georgin J., Franco D. S. P., Netto M. S., Allasia D., Oliveira M. L. S., Dotto G. L., Evaluation of Ocotea puberula bark powder (OPBP) as an effective adsorbent to uptake crystal violet from colored effluents: Alternative kinetic approaches, Environmental Science and Pollution Research, 27, p. 25727-25739, 2020.
[10]. Chevallier A., Encyclopedia of Herbal Medicine: 550 Herbs and Remedies for Common Ailments, 3rd ed., DK Publishing: New York, NY, USA, p. 264, 2016.
[11]. Chwil M., Kostryco M., Histochemical assays of secretory trichomes and the structure and content of mineral nutrients in Rubus idaeus L. leaves, Protoplasma, 257, p. 119-139, 2020.
[12]. Yang Y., Yin X., Zhang D., Lu J., Wang X., Isolation, Structural Characterization and Macrophage Activation Activity of an Acidic Polysaccharide from Raspberry Pulp, Molecules, 27, 1674, 2022.
[13]. Mosoarca G., Popa S., Vancea C., Dan M., Boran S., Removal of Methylene Blue from Aqueous Solutions Using a New Natural Lignocellulosic Adsorbent - Raspberry (Rubus idaeus) Leaves Powder, Polymers, 14, 1966, 2022.
[14]. Piccin J. S., Cadaval T. R. S., de Pinto L. A. A., Dotto G. L., Adsorption isotherms in liquid phase: Experimental, modeling and interpretations, In: Adsorption Processes for Water Treatment and Purification, Bonilla-Petriciolet A., Mendoza-Castillo D., Reynel-Avila H. (Eds.), Springer, Switzerland, p. 19-51, 2017.
[15]. Fabryanty R., Valencia C., Soetaredjo F. E., Putro J. N., Santoso S.P., Kurniawan A., Ju Y. H., Ismadji S., Removal of crystal violet dye by adsorption using bentonite - alginate composite, Journal of Environmental Chemical Engineering, 5(6), p. 5677-5687, 2017.
[16]. Filho A. C. D., Mazzocato A. C., Dotto G. L., Thue P. S., Pavan F. A., Eragrostis plana Nees as a novel eco-friendly adsorbent for removal of crystal violet from aqueous solutions, Environmental Science and Pollution Research, 24, p. 19909-19919, 2017.
[17]. Keereerak A., Chinpa W., A potential biosorbent from Moringa oleifera pod husk for crystal violet adsorption: Kinetics, isotherms, thermodynamic and desorption studies, Science Asia, 46, p. 186-194, 2020.
[18]. Jain S., Jayaram R. V., Removal of basic dyes from aqueous solution by low-cost adsorbent: Wood apple shell (Feronia acidissima), Desalination, 250(3), p. 921-927, 2010.
[19]. Silveira M. B., Pavan F. A., Gelos N. F., Lima E. C., Dias S. L., Punica granatum shell preparation, characterization, and use for crystal violet removal from aqueous solution, Clean-Soil Air Water, 42(7), p. 939-946, 2014.
[20]. Ahmad R., Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP), Journal of Hazardous Materials, 171, p. 767-773, 2009.
[21]. Wang X. S., Liu X., Wen L., Zhou Y., Jiang Y., Li Z., Comparison of Basic Dye Crystal Violet Removal from Aqueous Solution by Low-Cost Biosorbents, Separation Science and Technology, 43, p. 3712-3731, 2008.
[22]. Muhammad U. L., Zango Z. U., Kadir H. A., Usman A., Crystal violet removal from aqueous solution using corn stalk biosorbent, Science World Journal, 14, p. 133-138, 2019.
[23]. Mosoarca G., Vancea C., Popa S., Boran S., Optimization of crystal violet adsorption on common lilac tree leaf powder as natural adsorbent material, Global NEST Journal, 24(1), p. 87-96, 2022.
[24]. Saha P. D., Chakraborty S., Chowdhury S., Batch and continuous (fixed-bed column) bisorption of crystal violet by Artocarpus heterophyllus (jackfruit) leaf powder, Colloids and Surfaces B: Biointerfaces, 92, p. 262-270, 2012.
[25]. Chakraborty S., Chowdhury S., Saha P. D., Insight into biosorption equilibrium, kinetics and thermo-dynamics of crystal violet onto Ananas comosus (pineapple) leaf powder, Applied Water Science, 2, p. 135-141, 2012.
[26]. Kulkarni M. R., Revanth T., Anirudh A., Bhat P., Removal of crystal violet dye from aqueous solution using water hyacinth: equilibrium, kinetics and thermodynamics study, Resource-Efficient Technologies, 3(1), p. 71-77, 2017.
[28]. Saeed A., Sharif M., Iqbal M., Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption, Journal of Hazardous Materials, 179(1-3), p. 564-572, 2010.
[29]. Nieva A. D., Avena L. G. S., Pascual M. A. M., Pamintuan K. R. S., Characterization of Powdered Pineapple (Ananas comosus) Crown Leaves as Adsorbent for Crystal Violet in Aqueous Solutions, IOP Conf. Series: Earth and Environmental Science, 563, 012010, 2020.
Published
2022-06-15
How to Cite
1.
MOSOARCA G, VANCEA C, POPA S, BORAN S, RADULESCU‑GRAD ME. Equilibrium Study Regarding Crystal Violet Dye Adsorption on Raspberry Leaves Powder. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Jun.2022 [cited 8Nov.2024];45(2):38-4. Available from: https://gup.ugal.ro/ugaljournals/index.php/mms/article/view/5385
Issue
Section
Articles
