Corrosion Inhibition Efficacy of Hybrid Organic Extracts from Prosopisafricana and Citrulluslanatus on Mild Steel in Acidic Medium
Keywords:
hybrid, green inhibitor, prosopis africana, citrulluslanatus, inhibition efficiency
Abstract
Each of Prosopis Africana pod extract (PAPE) and Citrulluslanatus (WMPE) performed quite well as green inhibitors in the electrochemical corrosion in acidic solution at ambient temperature in previous research. However, the hybridization of these compounds was varied with the concentration ratio in this study to optimize the efficiency of the green inhibitor in a hydrochloric acid medium using mild steel. The extraction process of the inhibitor samples was carried out with the Soxhlet apparatus using n-hexane as the solvent. Furthermore, the potential inhibition efficiency was monitored using various corrosion measurement techniques at room temperature. The inhibitive response of the extracts could be attributed to the adsorption of the extracts’ components on mild steel surface by physisorption mechanism according to the Langmuir adsorption isotherm model. The results revealed that inhibition efficiency (IE%) depends on the concentration of the extracts. The peak IE% values were obtained with a hybrid ratio of 3:1 (PAPE: WMPE) for gravimetric technique. The Tafel polarization and gasometrical measurement technique is 96.7%, 98.5% and 83.1% respectively at the concentration of 1.0 g/L, which are above the peak IE% for PAPE (93.7%, 80.96% and 77.8%) and WMPE (92.7%, 80.5% and 75.6%).
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References
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[3]. Thangamalathi S., Anuradha V., Role of inorganic pollutants in freshwater ecosystem - A review, International Journal of Advanced Research in Biological Sciences, 5(11), p. 39-49, 2018.
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[15]. Shuaib-Babata Y. L., Ayinde I. V., Ameen M. O., Busari Y. O., Ambali I. O., Abdulraman S. O., Ajao K, S., Performance and corrosion inhibitive mechanism of Prosopis Africana pod extracts on mild steel in acidic medium, Uniport Journal of Engineering and Scientific Research (UJESR), 6 (2), p. 34-43, 2022.
[16]. Al-Senani G. M., Corrosion inhibition of carbon steel in acidic chloride medium by cucumissativus (cucumber) peel extract, International Journal of Electrochemical Science 11, p. 291-302, 2016.
[18]. ***, ASTM G4 - 95, Standard guide for conducting corrosion coupon test in field application, p. 44-53, United States: ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, 1995.
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[20]. ***, NACE/ ASTM G31- 12a, Standard guide for laboratory immersion corrosion testing of metals, United States: ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, 2012.
[20]. Bruce R. S., Introduction to the selection of carbon and lowalloy steels, In Welding, brazing, and soldering (David L. O., Thomas A. S., Stephen L., Glen R. E. Eds), vol. 6, ASM International, DOI: https://doi.org/10.31399/asm.hb.v06.a0001404, 1993.
[21]. Michael E. M., David E. L., Phase diagram and physical properties of low-C Steels, in physical metallurgy (Fifth edition), Elsievier, United States of America, 2014.
[22]. Jon L. D., Classification of carbon and low-alloy steels, in practical heat treating: basic principles, ASM International, ASM Technical Books DOI: https://doi.org/10.31399/asm.tb.phtbp.t59310095, 2020.
[23]. ***, Total Materia, Classification of carbon and low-alloy steels, Retrieved from https://www.totalmateria.com/page.aspx?ID=CheckArticle&site=kts&NM=62, Accessed on January 21, 2023.
[24]. Bob C., Carbon metal content, Classification of Steel and Alloy Steels, Retrieved from https://www.thefabricator.com/thewelder/article/metalsmaterials/carbon-metal-content-classification-of-steel-and-alloy-steels, Accessed on January 21, 2023.
[25]. Leeco Steel, The Different Categories of Carbon Steel Plate: What is Carbon Steel?, Retrieved from https://www.leecosteel.com/news/post/carbon-steel-categories/, Accessed on January 21, 2023.
[26]. Odusote J. K., Owalude D., Olusegun S., Yahya, R., Inhibition efficiency of moringa oleifera leaf extract on the corrosion of reinforced steel bar in HCl solution, The West Indian J. Eng, 38(2), p. 64-70, 2016.
[27]. Shuaib-Babata Y. L., Busari Y. O., Yahya R. A., Abdul J. M., Corrosion inhibition of AISI 1007 steel in hydrochloric acid using cucumissativus (cucumber) extracts as green inhibitor, ACTA Technica Corviniensis – Bulletin of Engineering, XI(4), p. 153-161, 2018.
Published
2023-03-15
How to Cite
1.
SHUAIB-BABATA YL, AYINDE IV, BUSARI YO, AMEEN MO, YAHYA RA, AMBALI IO, AREMU IN, ABDULRAMAN SO, AJAO KS, GARUBA AA. Corrosion Inhibition Efficacy of Hybrid Organic Extracts from Prosopisafricana and Citrulluslanatus on Mild Steel in Acidic Medium. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Mar.2023 [cited 22Dec.2024];46(1):21-2. Available from: https://gup.ugal.ro/ugaljournals/index.php/mms/article/view/6001
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