Influence of the Anodic Oxidation Treatment on the Corrosion Behaviour of Aluminium and Aluminium Alloys

  • Valentin DUMITRAŞCU "Dunarea de Jos" University of Galati
  • Lidia BENEA "Dunarea de Jos" University of Galati
Keywords: anodic oxidation, aluminium, corrosion, aluminium alloy

Abstract

This paper deals with the effect of anodic oxidation treatment on the corrosion behaviour of 6061 aluminium alloy in natural sea water. Anodic oxidation treatment leads to the formation of an amorphous oxide layer on the top surface of 6061 aluminium alloy as shown by optical microscopy results. The corrosion behaviour was investigated in natural sea water, harvested from the Black Sea, Mangalia harbour. The study was done by in situ electrochemical methods such as: open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PD) and cyclic voltammetry polarization (CV). The results show that the untreated 6061 aluminium alloy undergoes severe corrosion in natural sea water in comparison with anodized 6061 aluminium alloy. The results obtained by different electrochemical methods were in good agreement with each other and showed an improved corrosion resistance of the anodic oxide layer formed on aluminium alloy in natural sea water. The results were confirmed by optical microscopy.

Creative Commons License

Downloads

Download data is not yet available.

References

[1]. K. R. Padmavathi, R. Ramakrishnan, Tribological behaviour of aluminium hybrid metal matrix composite, Procedia Engineering, 97, p. 660-667, 2014.
[2]. R. Grilli, M. A. Baker, J. E. Castle, B. Dunn, J. F. Watts, Corrosion behaviour of a 2219 aluminium alloy treated with chromate conversion coating exposed to a 3.5% NaCl solution, Corrosion Science, 53, p. 1214-1223, 2011.
[3]. J. Y. Wang, C. Li, C. Y. Yin, Y. H. Wang, S. L. Zheng, Ultrasmall nanopores obtained by electric field enhance one-step anodization of aluminium alloy, Surface & Coatings Technology, 258, p. 615-623, 2014.
[4]. M. Curioni, P. Skeldon, G. E. Thompson, Chapter 5–Anodized anti-corrosion coatings for aluminium using rare earth metals, from Rare-earth based corrosion inhibitors, Edited by: M. Forsyth and B. Hinton, Woodhead Publishing Series in Metals and Surface Engineering, ISBN: 978-0-85709-347-9, 2014.
[5]. N. Birbilis, B. Hinton, Chapter 19 – Corrosion and corrosion protection of aluminium, from Fundamentals of aluminium metallurgy – production, processing and applications, Edited by: R. Lumley, Woodhead Publishing Series in Materials, ISBN: 978-0-85709-025-6, 2011.
[6]. H. Ezuber, A. El-Houd, F. El-Shawesh, A study on the corrosion behaviour of aluminium alloys in seawater, Materials and Design, 29, p. 801-805, 2008.
[7]. J. Ryl, J. Wysocka, M. Jarzynka, A. Zielinsky, J. Orlikowski, K. Darowicki, Effect of native air-formed oxidation on the corrosion behaviour of AA 7075 aluminium alloys, Corrosion Science, 87, p. 150-155, 2014.
[8]. M. Garcia-Rubio, P. Ocon, M. Curioni, G.E. Thompson, P. Skeldon, A. Lavia, I. Garcia, Degradation of the corrosion resistance of anodic oxide films through immersion in the anodizing electrolyte, Corrosion Science, 52, p. 2219-2227, 2010.
[9]. F. J. Garcia-Garcia, P. Skeldon, G. E. Thompson, G. C. Smith, The effect of nickel on alloy microstructure and electrochemical behaviour of AA1050 aluminium alloy in acid and alkaline solutions, Electrochimica Acta, 75, p. 229-238, 2012.
[10]. L. Benea, E. Mardare-Danaila, M. Mardare, J. P. Celis, Preparation of titanium oxide and hydroxyapatite on Ti–6Al–4V alloy surface and electrochemical behaviour in bio-simulated fluid solution, Corrosion Science, 80, p. 331-338, 2014.
[11]. M. Mubarak Ali, V. Raj, Formation and characterization of ceramic nanocomposite crystalline coatings on aluminium by anodization, Journal of Materials Science & Technology, 29(7), p. 595-602, 2013.
[12]. B. Zaid, D. Saidi, A. Benzaid, S. Hadji, Effects of pH and chloride concentration on pitting corrosion of AA6061 aluminium alloy, Corrosion Science, 50, p. 1841-1847, 2008.
Published
2015-09-15
How to Cite
1.
DUMITRAŞCU V, BENEA L. Influence of the Anodic Oxidation Treatment on the Corrosion Behaviour of Aluminium and Aluminium Alloys. The Annals of “Dunarea de Jos” University of Galati. Fascicle IX, Metallurgy and Materials Science [Internet]. 15Sep.2015 [cited 16Nov.2024];38(3):10-5. Available from: https://gup.ugal.ro/ugaljournals/index.php/mms/article/view/1296
Section
Articles

Most read articles by the same author(s)